SAFETY DATA SHEET
DOW AGROSCIENCES S.A.S.

Product name: INDAR™ 5EW Fungicide	Issue Date: 03/08/2018Print Date: 03/08/2018	
DOW AGROSCIENCES S.A.S. encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document.  We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions.

1. PRODUCT AND COMPANY IDENTIFICATION
Product name: INDAR™ 5EW Fungicide

Recommended use of the chemical and restrictions on use
Identified uses: Plant Protection Product  

COMPANY IDENTIFICATION
DOW AGROSCIENCES S.A.S.
371, RUE LUDWIG VAN BEETHOVEN
06560 VALBONNE
FRANCE

Customer Information Number:(0) 493 95 60 00
SDSQuestion@dow.com
Emergency telephone number
24-Hour Emergency Contact: 0033 388 736 000
Local Emergency Contact: 00 31 115 69 4982

2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
Skin irritation - Category 2 - H315
Eye irritation - Category 2 - H319
Chronic aquatic toxicity - Category 2 - H411
For the full text of the H-Statements mentioned in this Section, see Section 16.

Label elements

Hazard pictograms

Signal word: Warning

Hazard statements
H315	Causes skin irritation.	H319	Causes serious eye irritation.	H411	Toxic to aquatic life with long lasting effects.	
Precautionary statements
P280	Wear protective gloves/ protective clothing/ eye protection/ face protection.	P302 + P352	IF ON SKIN: Wash with plenty of soap and water.	P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.	P501	Dispose of contents/container in accordance with applicable regulations.	
Supplemental information
EUH401	To avoid risks to human health and the environment, comply with the instructions for use.	

Other hazards
No data available
3. COMPOSITION/INFORMATION ON INGREDIENTS

This product is a mixture.
CASRN / 
EC-No. / 
Index-No.Concentration	Component	Classification	CASRN
114369-43-6
EC-No.
406-140-2
Index-No.
608-023-00-3	5.0%	Fenbuconazole (ISO)	STOT RE - 2 - H373
Aquatic Acute - 1 - H400
Aquatic Chronic - 1 - H410
	CASRN
64742-94-5
EC-No.
265-198-5
Index-No.
649-424-00-3	> 40.0 - < 50.0 %	Solvent naphtha (petroleum), heavy aromatic	Asp. Tox. - 1 - H304
Aquatic Chronic - 2 - H411
	CASRN
108-94-1
EC-No.
203-631-1
Index-No.
606-010-00-7	> 10.0 - < 20.0 %	Cyclohexanone	Flam. Liq. - 3 - H226
Acute Tox. - 4 - H302
Acute Tox. - 4 - H332
Acute Tox. - 3 - H311
Skin Irrit. - 2 - H315
Eye Dam. - 1 - H318
	CASRN
57-55-6
EC-No.
200-338-0
Index-No.
 – 	< 5.0 %	Propylene glycol	Not classified	CASRN
68953-96-8
EC-No.
273-234-6
Index-No.
 – 	< 5.0 %	Benzenesulfonic acid, mono-C11-13-branched alkyl derivs., calcium salts	Acute Tox. - 4 - H312
Skin Irrit. - 2 - H315
Eye Dam. - 1 - H318
Aquatic Chronic - 2 - H411
	CASRN
64742-95-6
EC-No.
265-199-0
Index-No.
649-356-00-4	< 5.0 %	Solvent naphtha (petroleum), light aromatic	Flam. Liq. - 3 - H226
STOT SE - 3 - H335
STOT SE - 3 - H336
Asp. Tox. - 1 - H304
Aquatic Chronic - 2 - H411
	CASRN
91-20-3
EC-No.
202-049-5
Index-No.
601-052-00-2	< 1.0 %	Naphthalene	Acute Tox. - 4 - H302
Carc. - 2 - H351
Aquatic Acute - 1 - H400
Aquatic Chronic - 1 - H410
	CASRN
64742-94-5
EC-No.
265-198-5
Index-No.
649-424-00-3	< 1.0 %	Heavy aromatic naphtha	STOT SE - 3 - H336
Asp. Tox. - 1 - H304
Aquatic Chronic - 2 - H411
	For the full text of the H-Statements mentioned in this Section, see Section 16.

4. FIRST AID MEASURES
Description of first aid measures
General advice: First Aid responders should pay attention to self-protection and use the recommended protective clothing (chemical resistant gloves, splash protection).  If potential for exposure exists refer to Section 8 for specific personal protective equipment.  

Inhalation: Move person to fresh air. If person is not breathing, call an emergency responder or ambulance, then give artificial respiration; if by mouth to mouth use rescuer protection (pocket mask etc). Call a poison control center or doctor for treatment advice.  If breathing is difficult, oxygen should be administered by qualified personnel.  

Skin contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice.  Suitable emergency safety shower facility should be available in work area.  

Eye contact: Hold eyes open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eyes. Call a poison control center or doctor for treatment advice.  Suitable emergency eye wash facility should be available in work area.  

Ingestion: Immediately call a poison control center or doctor. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give any liquid to the person. Do not give anything by mouth to an unconscious person.  

Most important symptoms and effects, both acute and delayed: Aside from the information found under Description of first aid measures (above) and Indication of immediate medical attention and special treatment needed (below), any additional important symptoms and effects are described in Section 11: Toxicology Information.

Indication of any immediate medical attention and special treatment needed
Notes to physician: Repeated excessive exposure may aggravate preexisting lung disease.  Maintain adequate ventilation and oxygenation of the patient.  May cause asthma-like (reactive airways) symptoms.  Bronchodilators, expectorants, antitussives and corticosteroids may be of help.  If burn is present, treat as any thermal burn, after decontamination.  Due to irritant properties, swallowing may result in burns/ulceration of mouth, stomach and lower gastrointestinal tract with subsequent stricture. Aspiration of vomitus may cause lung injury. Suggest endotracheal/esophageal control if lavage is done.  Probable mucosal damage may contraindicate the use of gastric lavage.  No specific antidote.  Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient.  Have the Safety Data Sheet, and if available, the product container or label with you when calling a poison control center or doctor, or going for treatment.  

5. FIREFIGHTING MEASURES
Suitable extinguishing media: To extinguish combustible residues of this product use water fog, carbon dioxide, dry chemical or foam.  Dry chemical fire extinguishers.  Carbon dioxide fire extinguishers.  Foam.  Alcohol resistant foams (ATC type) are preferred. General purpose synthetic foams (including AFFF) or protein foams may function, but will be less effective.  

Unsuitable extinguishing media: No data available

Special hazards arising from the substance or mixture
Hazardous combustion products: During a fire, smoke may contain the original material in addition to combustion products of varying composition which may be toxic and/or irritating.  Combustion products may include and are not limited to:  Hydrogen chloride.  Carbon monoxide.  Carbon dioxide.  

Unusual Fire and Explosion Hazards:   This material will not burn until the water has evaporated. Residue can burn.  Container may rupture from gas generation in a fire situation.  Dense smoke is produced when product burns.  

Advice for firefighters
Fire Fighting Procedures: Keep people away.  Isolate fire and deny unnecessary entry.  Use water spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has passed.  Fight fire from protected location or safe distance. Consider the use of unmanned hose holders or monitor nozzles.  Immediately withdraw all personnel from the area in case of rising sound from venting safety device or discoloration of the container.  Burning liquids may be extinguished by dilution with water.  Move container from fire area if this is possible without hazard.  Burning liquids may be moved by flushing with water to protect personnel and minimize property damage.  To extinguish combustible residues of this product use water fog, carbon dioxide, dry chemical or foam.  Contain fire water run-off if possible. Fire water run-off, if not contained, may cause environmental damage.  Review the "Accidental Release Measures" and the "Ecological Information" sections of this (M)SDS.  

Special protective equipment for firefighters: Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves).  If protective equipment is not available or not used, fight fire from a protected location or safe distance.  

6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures: Isolate area.  Keep unnecessary and unprotected personnel from entering the area.  Keep upwind of spill.  Ventilate area of leak or spill.  No smoking in area.  Refer to section 7, Handling, for additional precautionary measures.  Use appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection.  

Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information.  

Methods and materials for containment and cleaning up: Contain spilled material if possible.  Small spills:  Absorb with materials such as:  Clay.  Dirt.  Sand.  Sweep up.  Collect in suitable and properly labeled containers.  Large spills:  Contact Dow AgroSciences for clean-up assistance.  See Section 13, Disposal Considerations, for additional information.  

7. Handling and storage
Precautions for safe handling: Keep out of reach of children.  Keep away from heat, sparks and flame.  Avoid contact with eyes, skin, and clothing.  Avoid breathing vapor or mist.  Do not swallow.  Wash thoroughly after handling.  Keep container closed.  Use with adequate ventilation.  Containers, even those that have been emptied, can contain vapors. Do not cut, drill, grind, weld, or perform similar operations on or near empty containers.  Spills of these organic materials on hot fibrous insulations may lead to lowering of the autoignition temperatures possibly resulting in spontaneous combustion.  

Conditions for safe storage: Store in a dry place.  Store in original container.  Keep container tightly closed when not in use.  Do not store near food, foodstuffs, drugs or potable water supplies.  

Storage stability: To maintain product quality, recommended storage temperature is  > 0 °C  

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
If exposure limits exist, they are listed below.  If no exposure limits are displayed, then no values are applicable.
Component	Regulation	Type of listing	Value/Notation	Solvent naphtha (petroleum), heavy aromatic	ACGIH	TWA 	200 mg/m3  , total hydrocarbon vapor		Dow IHG	TWA 	100 mg/m3  		Dow IHG	STEL 	300 mg/m3  	Cyclohexanone	ACGIH	TWA 	  20 ppm		ACGIH	STEL 	  50 ppm		ACGIH	TWA 	   SKIN		ACGIH	STEL 	   SKIN		Dow IHG	TWA 	  7.5 ppm		Dow IHG	TWA 	   SKIN		Dow IHG	STEL 	  15 ppm		Dow IHG	STEL 	   SKIN		2000/39/EC	TWA 	40.8 mg/m3  10 ppm		2000/39/EC	TWA 	   SKIN		2000/39/EC	STEL 	81.6 mg/m3  20 ppm		2000/39/EC	STEL 	   SKIN	Propylene glycol	US WEEL	TWA 	10 mg/m3  	Solvent naphtha (petroleum), light aromatic	ACGIH	TWA 	200 mg/m3  , total hydrocarbon vapor		Dow IHG	TWA 	100 mg/m3  		Dow IHG	STEL 	300 mg/m3  	Naphthalene	ACGIH	TWA 	  10 ppm		ACGIH	TWA 	   SKIN		Dow IHG	TWA 	  10 ppm		Dow IHG	TWA 	   SKIN		Dow IHG	STEL 	  15 ppm		Dow IHG	STEL 	   SKIN		91/322/EEC	TWA 	50 mg/m3  10 ppm	Heavy aromatic naphtha	ACGIH	TWA 	200 mg/m3  , total hydrocarbon vapor		Dow IHG	TWA 	100 mg/m3  		Dow IHG	STEL 	300 mg/m3  	
RECOMMENDATIONS IN THIS SECTION ARE FOR MANUFACTURING, COMMERCIAL BLENDING AND PACKAGING WORKERS. APPLICATORS AND HANDLERS SHOULD SEE THE PRODUCT LABEL FOR PROPER PERSONAL PROTECTIVE EQUIPMENT AND CLOTHING.  

Biological occupational exposure limits
Components	CAS-No.	Control parameters	Biological specimen	Sampling time	Permissible concentration	Basis
Cyclohexanone108-94-1				100 mg/g		
	1,2-Cyclohexanediol	Urine	End of shift at end of workweek	80 mg/l	ACGIH BEI	
	Cyclohexanol	Urine	End of shift (As soon as possible after exposure ceases)	8 mg/l	ACGIH BEI	

Exposure controls
Engineering controls: Use engineering controls to maintain airborne level below exposure limit requirements or guidelines.  If there are no applicable exposure limit requirements or guidelines, use only with adequate ventilation.  Local exhaust ventilation may be necessary for some operations.  

Individual protection measures
Eye/face protection: Use chemical goggles.  Chemical goggles should be consistent with EN 166 or equivalent.  
Skin protection
Hand protection: Use chemical resistant gloves classified under Standard EN374: Protective gloves against chemicals and micro-organisms.  Examples of preferred glove barrier materials include:  Polyethylene.  Ethyl vinyl alcohol laminate ("EVAL").  Polyvinyl chloride ("PVC" or "vinyl").  Styrene/butadiene rubber.  Viton.  Examples of acceptable glove barrier materials include:  Butyl rubber.  Chlorinated polyethylene.  Natural rubber ("latex").  Neoprene.  Nitrile/butadiene rubber ("nitrile" or "NBR").  When prolonged or frequently repeated contact may occur, a glove with a protection class of 4 or higher (breakthrough time greater than 120 minutes according to EN 374) is recommended.  When only brief contact is expected, a glove with a protection class of 1 or higher (breakthrough time greater than 10 minutes according to EN 374) is recommended.  NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier.  
Other protection: Use protective clothing chemically resistant to this material.  Selection of specific items such as face shield, boots, apron, or full body suit will depend on the task.  
Respiratory protection: Respiratory protection should be worn when there is a potential to exceed the exposure limit requirements or guidelines.  If there are no applicable exposure limit requirements or guidelines, use an approved respirator.  Selection of air-purifying or positive-pressure supplied-air will depend on the specific operation and the potential airborne concentration of the material.  For emergency conditions, use an approved positive-pressure self-contained breathing apparatus.  
Use the following CE approved air-purifying respirator:  Organic vapor cartridge with a particulate pre-filter, type AP2.  

See SECTION 7: Handling and storage and SECTION 13: Disposal considerations for measures to prevent excessive environmental exposure during use and waste disposal.

9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Physical state	Liquid.  	ColorWhite to tan  Odor	Aromatic  	Odor Threshold	No test data available  	pH	7.3   1% pH Electrode (1% aqueous suspension)Melting point/range	Not applicableFreezing point	No test data availableBoiling point (760 mmHg)	No test data availableFlash point	closed cup 74 °C Pensky-Martens Closed Cup ASTM D 93 Evaporation Rate (Butyl Acetate = 1)	No test data availableFlammability (solid, gas)	Not ApplicableLower explosion limit	No test data available  Upper explosion limit	No test data available  Vapor Pressure	 No test data availableRelative Vapor Density (air = 1)	No test data available 	Relative Density (water = 1)	1.01  at 20 °C Digital Density Meter (Oscillating Coil) 	Water solubility	emulsifiable  	Partition coefficient: n-octanol/water	No data available  	Auto-ignition temperature	No test data available  	Decomposition temperature	No test data available  	Dynamic Viscosity	No test data available	Kinematic Viscosity	No test data available	Explosive properties	No 	Oxidizing properties	No significant increase (>5C) in temperature. 	Liquid Density	1.01 g/cm3 at 20 °C Digital density meter 	Molecular weight	No data available	
NOTE:  The physical data presented above are typical values and should not be construed as a specification.
10. STABILITY AND REACTIVITY
Reactivity: No dangerous reaction known under conditions of normal use.  

Chemical stability: Thermally stable at typical use temperatures.  

Possibility of hazardous reactions: Polymerization will not occur.  
 
Conditions to avoid: Active ingredient decomposes at elevated temperatures.  Generation of gas during decomposition can cause pressure in closed systems.  

Incompatible materials: Avoid contact with:  Strong acids.  Strong oxidizers.  

Hazardous decomposition products:  Decomposition products depend upon temperature, air supply and the presence of other materials.  Decomposition products can include and are not limited to:  Hydrogen chloride.  
11. TOXICOLOGICAL INFORMATION

Toxicological information appears in this section when such data is available. 

Acute toxicity
Acute oral toxicity
Very low toxicity if swallowed.  Harmful effects not anticipated from swallowing small amounts.  Swallowing may result in gastrointestinal irritation or ulceration.  

As product:  Single dose oral LD50 has not been determined.  For similar material(s):  
LD50. Rat. > 2,000 mg/kg  No deaths occurred at this concentration.  

Acute dermal toxicity
Prolonged skin contact is unlikely to result in absorption of harmful amounts.  

As product:  The dermal LD50 has not been determined.  For similar material(s):  
LD50. Rabbit. > 2,000 mg/kg No deaths occurred at this concentration.  

Acute inhalation toxicity
Prolonged excessive exposure to mist may cause adverse effects.  Excessive exposure may cause irritation to upper respiratory tract (nose and throat) and lungs.  May cause central nervous system effects.  Symptoms of excessive exposure may be anesthetic or narcotic effects; dizziness and drowsiness may be observed.  May cause nausea and vomiting.  
As product:  The LC50 has not been determined.  

Skin corrosion/irritation
Brief contact may cause slight skin irritation with local redness.
May cause drying and flaking of the skin.

Serious eye damage/eye irritation
May cause severe eye irritation.
May cause slight corneal injury.

Sensitization
For similar material(s):
Did not cause allergic skin reactions when tested in guinea pigs.

For respiratory sensitization:
No relevant data found.

Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.

Specific Target Organ Systemic Toxicity (Repeated Exposure)
For the active ingredient(s):
In animals, effects have been reported on the following organs:
Liver.

Based on information for component(s):
In animals, effects have been reported on the following organs:
Central nervous system.
Kidney.
Liver.
Gastrointestinal tract.
Thyroid.
Urinary tract.
Lung.
Symptoms of excessive exposure may be anesthetic or narcotic effects; dizziness and drowsiness may be observed.

Carcinogenicity
For the active ingredient(s):  Has caused cancer in laboratory animals.  However, the effects are species specific and are not relevant to humans.  

Teratogenicity
For the active ingredient(s):  Has been toxic to the fetus in laboratory animals at doses toxic to the mother.  Did not cause birth defects in laboratory animals.  

Reproductive toxicity
For the active ingredient(s):  In animal studies, has been shown to interfere with reproduction in females.  

Cyclohexanone caused reduced growth and survival of offspring in an animal reproduction study. Dose levels producing this effect also caused central nervous system effects in parental animals.  In animal studies, has been shown to interfere with reproduction in males.  Effects have been seen only at doses that produced significant toxicity to the parent animals.  

Mutagenicity
For the active ingredient(s):  In vitro genetic toxicity studies were negative.  Animal genetic toxicity studies were negative.  

Based on information for component(s):  In vitro genetic toxicity studies were negative in some cases and positive in other cases.  Animal genetic toxicity studies were negative in some cases and positive in other cases.  

Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard.  

Components influencing toxicology:
 
Fenbuconazole (ISO)
Acute inhalation toxicity 
Prolonged excessive exposure to dust may cause adverse effects.  Based on the available data, respiratory irritation was not observed.  
 
LC50. Rat. male and female. 4 Hour. dust/mist. > 2.10 mg/l 
 
Maximum attainable concentration.  No deaths occurred at this concentration.  
 
Solvent naphtha (petroleum), heavy aromatic
Acute inhalation toxicity 
For similar material(s):  LC50. Rat. 4 Hour. dust/mist. > 5.28 mg/l 
 
Cyclohexanone
Acute inhalation toxicity 
Vapor concentrations are attainable which could be hazardous on single exposure.  May cause central nervous system effects.  Excessive exposure may cause severe irritation to upper respiratory tract (nose and throat) and lungs.  
 
LC50. Rat. 4 Hour. vapour. > 6.2 mg/l No deaths occurred at this concentration.  
 
Propylene glycol
Acute inhalation toxicity 
Mist may cause irritation of upper respiratory tract (nose and throat).  LC50. Rabbit. 2 Hour. dust/mist. 317.042 mg/l No deaths occurred at this concentration.  
 
Benzenesulfonic acid, mono-C11-13-branched alkyl derivs., calcium salts
Acute inhalation toxicity 
The LC50 has not been determined.  
 
Solvent naphtha (petroleum), light aromatic
Acute inhalation toxicity 
Vapor concentrations are attainable which could be hazardous on single exposure.  May cause respiratory irritation and central nervous system depression.  Symptoms may include headache, dizziness and drowsiness, progressing to incoordination and unconsciousness.  
 
LC50. Rat. 4 Hour. vapour. > 10.2 mg/l 
 
Naphthalene
Acute inhalation toxicity 
Excessive exposure may cause irritation to upper respiratory tract (nose and throat).  Excessive exposure may cause lung injury.  Signs and symptoms of excessive exposure may include:  Headache.  Confusion.  Sweating.  Nausea and/or vomiting.  
 
LC50. Rat. 4 Hour. vapour. > 0.41 mg/l The LC50 value is greater than the Maximum Attainable Concentration.  
 
Heavy aromatic naphtha
Acute inhalation toxicity 
Prolonged excessive exposure may cause adverse effects.  May cause central nervous system effects.  Symptoms may include headache, dizziness and drowsiness, progressing to incoordination and unconsciousness.  
 
As product:  The LC50 has not been determined.  
 
For similar material(s):  LC50. Rat. 4 Hour. vapour. > 4.688 mg/l 
 
Maximum attainable concentration.  

12. ECOLOGICAL INFORMATION

Ecotoxicological information appears in this section when such data is available.

Toxicity
Acute toxicity to fish
Based on information for a similar material:
Material is toxic to aquatic organisms (LC50/EC50/IC50 between 1 and 10 mg/L in the most sensitive species).

For similar material(s):
LC50. Lepomis macrochirus (Bluegill sunfish). static test. 96 Hour. 11 mg/l

For similar material(s):
LC50. Oncorhynchus mykiss (rainbow trout). flow-through test. 96 Hour. 5.6 mg/l

Acute toxicity to aquatic invertebrates
For similar material(s):
EC50. Daphnia magna (Water flea). static test. 48 Hour. 9.3 mg/l

Acute toxicity to algae/aquatic plants
For similar material(s):
ErC50. alga Scenedesmus sp.. 72 Hour. Growth rate inhibition. 5.7 mg/l

Toxicity to Above Ground Organisms
Material is practically non-toxic to birds on an acute basis (LD50 > 2000 mg/kg).

Based on information for a similar material:

oral LD50. Colinus virginianus (Bobwhite quail). > 2250mg/kg bodyweight.

Based on information for a similar material:

contact LD50. Apis mellifera (bees). 48 d. > 100µg/bee

Based on information for a similar material:

oral LD50. Apis mellifera (bees). 48 d. > 95µg/bee

Toxicity to soil-dwelling organisms
LC50. Eisenia fetida (earthworms). Based on information for a similar material:. 14 d. 451 mg/kg

Persistence and degradability

Fenbuconazole (ISO)
Biodegradability: Material is expected to biodegrade very slowly (in the environment).  Fails to pass OECD/EEC tests for ready biodegradability.  
10-day Window: Fail  
Biodegradation:  17 % 
Exposure time: 28 d 
Method: OECD Test Guideline 301D or Equivalent  

Photodegradation
Atmospheric half-life: 13.1 Hour

Solvent naphtha (petroleum), heavy aromatic
Biodegradability: For similar material(s):  Biodegradation may occur under aerobic conditions (in the presence of oxygen).  Based on stringent OECD test guidelines, this material cannot be considered as readily biodegradable; however, these results do not necessarily mean that the material is not biodegradable under environmental conditions.  

Biodegradation:  58.6 % 
Exposure time: 28 d 
Method: OECD Test Guideline 301F  

Cyclohexanone
Biodegradability: Material is readily biodegradable.  Passes OECD test(s) for ready biodegradability.  
10-day Window: Not applicable  
Biodegradation:  87 % 
Exposure time: 14 d 
Method: OECD Test Guideline 301C or Equivalent  
10-day Window: Pass  
Biodegradation:  90 - 100 % 
Exposure time: 28 d 
Method: OECD Test Guideline 301F  

Propylene glycol
Biodegradability: Material is readily biodegradable.  Passes OECD test(s) for ready biodegradability.  Biodegradation may occur under anaerobic conditions (in the absence of oxygen).  
10-day Window: Pass  
Biodegradation:  81 % 
Exposure time: 28 d 
Method: OECD Test Guideline 301F or Equivalent  
10-day Window: Not applicable  
Biodegradation:  96 % 
Exposure time: 64 d 
Method: OECD Test Guideline 306 or Equivalent  

Benzenesulfonic acid, mono-C11-13-branched alkyl derivs., calcium salts
Biodegradability: Material is expected to biodegrade very slowly (in the environment).  Fails to pass OECD/EEC tests for ready biodegradability.  
10-day Window: Fail  
Biodegradation:  2.9 % 
Exposure time: 28 d 
Method: OECD Test Guideline 301E or Equivalent  

Solvent naphtha (petroleum), light aromatic
Biodegradability: For the major component(s):  Material is expected to biodegrade very slowly (in the environment).  Fails to pass OECD/EEC tests for ready biodegradability.  For some component(s):  Based on stringent OECD test guidelines, this material cannot be considered as readily biodegradable; however, these results do not necessarily mean that the material is not biodegradable under environmental conditions.  

Naphthalene
Biodegradability: Material is expected to be readily biodegradable.  

Heavy aromatic naphtha
Biodegradability: Material is inherently biodegradable (reaches > 20% biodegradation in OECD test(s) for inherent biodegradability).  

Bioaccumulative potential

Fenbuconazole (ISO)
Bioaccumulation: Bioconcentration potential is moderate (BCF between 100 and 3000 or Log Pow between 3 and 5).  
Partition coefficient: n-octanol/water(log Pow): 3.23 Measured 
Bioconcentration factor (BCF): 160  Lepomis macrochirus (Bluegill sunfish)  28 Hour  

Solvent naphtha (petroleum), heavy aromatic
Bioaccumulation: For similar material(s):  Bioconcentration potential is high (BCF > 3000 or Log Pow between 5 and 7).  

Cyclohexanone
Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3).  
Partition coefficient: n-octanol/water(log Pow): 0.81 Measured 

Propylene glycol
Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3).  
Partition coefficient: n-octanol/water(log Pow): -1.07 Measured 
Bioconcentration factor (BCF): 0.09      Estimated.

Benzenesulfonic acid, mono-C11-13-branched alkyl derivs., calcium salts
Bioaccumulation: Bioconcentration potential is moderate (BCF between 100 and 3000 or Log Pow between 3 and 5).  
Partition coefficient: n-octanol/water(log Pow): 4.6 OECD Test Guideline 107 or Equivalent 

Solvent naphtha (petroleum), light aromatic
Bioaccumulation: For the major component(s):  Bioconcentration potential is moderate (BCF between 100 and 3000 or Log Pow between 3 and 5).  For the minor component(s):  Bioconcentration potential is low (BCF < 100 or Log Pow < 3).  

Naphthalene
Bioaccumulation: Bioconcentration potential is moderate (BCF between 100 and 3000 or Log Pow between 3 and 5).  
Partition coefficient: n-octanol/water(log Pow): 3.3 Measured 
Bioconcentration factor (BCF): 40 - 300  Fish  28 d  Measured

Heavy aromatic naphtha
Bioaccumulation: For similar material(s):  Bioconcentration potential is high (BCF > 3000 or Log Pow between 5 and 7).  

Mobility in soil

Fenbuconazole (ISO)
Potential for mobility in soil is slight (Koc between 2000 and 5000).
Partition coefficient (Koc): 4425 

Solvent naphtha (petroleum), heavy aromatic
No data available.

Cyclohexanone
Potential for mobility in soil is very high (Koc between 0 and 50).
Partition coefficient (Koc): 15 Estimated.

Propylene glycol
Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is not expected to be an important fate process.
Potential for mobility in soil is very high (Koc between 0 and 50).
Partition coefficient (Koc): < 1 Estimated.

Benzenesulfonic acid, mono-C11-13-branched alkyl derivs., calcium salts
No relevant data found.

Solvent naphtha (petroleum), light aromatic
For the major component(s):
Potential for mobility in soil is low (Koc between 500 and 2000).

Naphthalene
Potential for mobility in soil is medium (Koc between 150 and 500).
Partition coefficient (Koc): 240 - 1300 Measured

Heavy aromatic naphtha
No relevant data found.

Results of PBT and vPvB assessment 

Fenbuconazole (ISO)
This substance is not considered to be persistent, bioaccumulating and toxic (PBT).  This substance is not considered to be very persistent and very bioaccumulating (vPvB).  

Solvent naphtha (petroleum), heavy aromatic
This substance is not considered to be persistent, bioaccumulating and toxic (PBT).  This substance is not considered to be very persistent and very bioaccumulating (vPvB).  

Cyclohexanone
This substance is not considered to be persistent, bioaccumulating and toxic (PBT).  This substance is not considered to be very persistent and very bioaccumulating (vPvB).  

Propylene glycol
This substance is not considered to be persistent, bioaccumulating and toxic (PBT).  This substance is not considered to be very persistent and very bioaccumulating (vPvB).  

Benzenesulfonic acid, mono-C11-13-branched alkyl derivs., calcium salts
This substance is not considered to be persistent, bioaccumulating and toxic (PBT).  This substance is not considered to be very persistent and very bioaccumulating (vPvB).  

Solvent naphtha (petroleum), light aromatic
This substance is not considered to be persistent, bioaccumulating and toxic (PBT).  This substance is not considered to be very persistent and very bioaccumulating (vPvB).  

Naphthalene
This substance has not been assessed for persistence, bioaccumulation and toxicity  (PBT).  

Heavy aromatic naphtha
This substance is not considered to be persistent, bioaccumulating and toxic (PBT).  This substance is not considered to be very persistent and very bioaccumulating (vPvB).  

Other adverse effects

Fenbuconazole (ISO)
This substance is not on the Montreal Protocol list of substances that deplete the ozone layer.

Solvent naphtha (petroleum), heavy aromatic
This substance is not on the Montreal Protocol list of substances that deplete the ozone layer.

Cyclohexanone
This substance is not on the Montreal Protocol list of substances that deplete the ozone layer.

Propylene glycol
This substance is not on the Montreal Protocol list of substances that deplete the ozone layer.

Benzenesulfonic acid, mono-C11-13-branched alkyl derivs., calcium salts
This substance is not on the Montreal Protocol list of substances that deplete the ozone layer.

Solvent naphtha (petroleum), light aromatic
This substance is not on the Montreal Protocol list of substances that deplete the ozone layer.

Naphthalene
This substance is not on the Montreal Protocol list of substances that deplete the ozone layer.

Heavy aromatic naphtha
This substance is not on the Montreal Protocol list of substances that deplete the ozone layer.

13. DISPOSAL CONSIDERATIONS
Disposal methods: 
If wastes and/or containers cannot be disposed of according to the product label directions, disposal of this material must be in accordance with your local or area regulatory authorities.  This information presented below only applies to the material as supplied.  The identification based on characteristic(s) or listing may not apply if the material has been used or otherwise contaminated.  It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste identification and disposal methods in compliance with applicable regulations.  If the material as supplied becomes a waste, follow all applicable regional, national and local laws.  

14. TRANSPORT INFORMATION

Classification for ROAD and Rail transport:
Proper shipping name	ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.(Fenbuconazole)	UN number	UN  3082	Class	9	Packing group	III	Environmental hazards	Fenbuconazole	

Classification for SEA transport (IMO-IMDG):
Proper shipping name	ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.(Fenbuconazole)	UN number	UN  3082	Class	9	Packing group	III	Marine pollutant	Fenbuconazole	Transport in bulk according to Annex I or II of MARPOL 73/78 and the IBC or IGC Code	Consult IMO regulations before transporting ocean bulk	
Classification for AIR transport (IATA/ICAO):
Proper shipping name	Environmentally hazardous substance, liquid, n.o.s.(Fenbuconazole)	UN number	UN  3082	Class	9	Packing group	III	

This information is not intended to convey all specific regulatory or operational requirements/information relating to this product.  Transportation classifications may vary by container volume and may be influenced by regional or country variations in regulations.  Additional transportation system information can be obtained through an authorized sales or customer service representative.  It is the responsibility of the transporting organization to follow all applicable laws, regulations and rules relating to the transportation of the material.

15. REGULATORY INFORMATION

Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances.
Listed in Regulation: ENVIRONMENTAL HAZARDS
Number in Regulation: E2
200 t
500 t

Classification and labeling have been performed according to Regulation (EC) No 1272/2008.
16. OTHER INFORMATION

Full text of H-Statements referred to under sections 2 and 3.
H226Flammable liquid and vapour.	H302Harmful if swallowed.	H304May be fatal if swallowed and enters airways.	H311Toxic in contact with skin.	H312Harmful in contact with skin.	H315Causes skin irritation.	H318Causes serious eye damage.	H319Causes serious eye irritation.	H332Harmful if inhaled.	H335May cause respiratory irritation.	H336May cause drowsiness or dizziness.	H351Suspected of causing cancer.	H373May cause damage to organs through prolonged or repeated exposure if swallowed.	H400Very toxic to aquatic life.	H410Very toxic to aquatic life with long lasting effects.	H411Toxic to aquatic life with long lasting effects.	
Revision
Identification Number: 269744 / A285 / Issue Date: 03/08/2018 / Version: 3.0
DAS Code: GF-1339
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this document.

Legend
2000/39/EC	Europe. Commission Directive 2000/39/EC establishing a first list of indicative occupational exposure limit values	91/322/EEC	Europe. Commission Directive 91/322/EEC on establishing indicative limit values	ACGIH	USA. ACGIH Threshold Limit Values (TLV)	ACGIH BEI	ACGIH - Biological Exposure Indices (BEI)	Dow IHG	Dow Industrial Hygiene Guideline	SKIN	Absorbed via skin	STEL	Short term exposure limit	TWA	8-hr TWA	US WEEL	USA. Workplace Environmental Exposure Levels (WEEL)	Acute Tox.	Acute toxicity	Aquatic Acute	Acute aquatic toxicity	Aquatic Chronic	Chronic aquatic toxicity	Asp. Tox.	Aspiration hazard	Carc.	Carcinogenicity	Eye Dam.	Serious eye damage	Flam. Liq.	Flammable liquids	Skin Irrit.	Skin irritation	STOT RE	Specific target organ toxicity - repeated exposure	STOT SE	Specific target organ toxicity - single exposure	
Full text of other abbreviations
ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways; ADR - European Agreement concerning the International Carriage of Dangerous Goods by Road; AICS - Australian Inventory of Chemical Substances; ASTM - American Society for the Testing of Materials; bw - Body weight; CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Canada); ECHA - European Chemicals Agency; EC-Number - European Community number; ECx - Concentration associated with x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; n.o.s. - Not Otherwise Specified; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RID - Regulations concerning the International Carriage of Dangerous Goods by Rail; SADT - Self-Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative

Information Source and References
This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from information supplied by internal references within our company.

DOW AGROSCIENCES S.A.S. urges each customer or recipient of this (M)SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this (M)SDS and any hazards associated with the product.  The information herein is provided in good faith and believed to be accurate as of the effective date shown above.  However, no warranty, express or implied, is given.  Regulatory requirements are subject to change and may differ between various locations. It is the buyer's/user's responsibility to ensure that his activities comply with all federal, state, provincial or local laws.  The information presented here pertains only to the product as shipped.  Since conditions for use of the product are not under the control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the safe use of this product.  Due to the proliferation of sources for information such as manufacturer-specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other than ourselves.  If you have obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current, please contact us for the most current version.    

IL