SAFETY DATA SHEET
DOW AGROSCIENCES S.A.S.

Product name: KARATHANE STAR™ 350EC Fungicide	Issue Date: 03/08/2018Print Date: 03/08/2018	
DOW AGROSCIENCES S.A.S. encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document.  We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions.

1. PRODUCT AND COMPANY IDENTIFICATION
Product name: KARATHANE STAR™ 350EC Fungicide

Recommended use of the chemical and restrictions on use
Identified uses: Plant Protection Product  

COMPANY IDENTIFICATION
DOW AGROSCIENCES S.A.S.
371, RUE LUDWIG VAN BEETHOVEN
06560 VALBONNE
FRANCE

Customer Information Number:(0) 493 95 60 00
SDSQuestion@dow.com
Emergency telephone number
24-Hour Emergency Contact: 0033 388 736 000
Local Emergency Contact: 00 31 115 69 4982

2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
Flammable liquids - Category 3 - H226
Acute toxicity - Category 4 - Oral - H302
Acute toxicity - Category 4 - Inhalation - H332
Eye irritation - Category 2 - H319
Skin sensitisation - Category 1 - H317
Specific target organ toxicity - single exposure - Category 3 - Narcotic effects. - H336
Acute aquatic toxicity - Category 1 - H400
Chronic aquatic toxicity - Category 1 - H410
For the full text of the H-Statements mentioned in this Section, see Section 16.

Label elements

Hazard pictograms

Signal word: Warning

Hazard statements
H226	Flammable liquid and vapour.	H302	Harmful if swallowed.	H332	Harmful if inhaled.	H319	Causes serious eye irritation.	H317	May cause an allergic skin reaction.	H336	May cause drowsiness or dizziness.	H410	Very toxic to aquatic life with long lasting effects.	
Precautionary statements
P280	Wear protective gloves/ protective clothing/ eye protection/ face protection.	P301 + P312	IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.	P302 + P352	IF ON SKIN: Wash with plenty of water.	P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.	P501	Dispose of contents/container in accordance with applicable regulations.	
Supplemental information
EUH401	To avoid risks to human health and the environment, comply with the instructions for use.	EUH066	Repeated exposure may cause skin dryness or cracking.			
ContainsMeptyldinocap; Hydrocarbons, C10, aromatics, <1% naphthalene

Other hazards
No data available
3. COMPOSITION/INFORMATION ON INGREDIENTS

This product is a mixture.
CASRN / 
EC-No. / 
Index-No.Concentration	Component	Classification	CASRN
131-72-6
EC-No.
 –
Index-No.
 – 	35.7%	Meptyldinocap	Flam. Liq. - 3 - H226
Acute Tox. - 4 - H332
Skin Sens. - 1B - H317
Aquatic Acute - 1 - H400
Aquatic Chronic - 1 - H410
	CASRN
64742-94-5
EC-No.
265-198-5
Index-No.
649-424-00-3	> 50.0 - < 60.0 %	Heavy aromatic naphtha	STOT SE - 3 - H336
Asp. Tox. - 1 - H304
Aquatic Chronic - 2 - H411
	CASRN
68953-96-8
EC-No.
273-234-6
Index-No.
 – 	< 5.0 %	Benzenesulfonic acid, mono-C11-13-branched alkyl derivs., calcium salts	Acute Tox. - 4 - H312
Skin Irrit. - 2 - H315
Eye Dam. - 1 - H318
Aquatic Chronic - 2 - H411
	CASRN
64742-94-5
EC-No.
265-198-5
Index-No.
649-424-00-3	< 5.0 %	Solvent naphtha (petroleum), heavy aromatic	Asp. Tox. - 1 - H304
Aquatic Chronic - 2 - H411
	CASRN
95-63-6
EC-No.
202-436-9
Index-No.
601-043-00-3	< 5.0 %	1,2,4-Trimethylbenzene	Flam. Liq. - 3 - H226
Acute Tox. - 4 - H332
Skin Irrit. - 2 - H315
Eye Irrit. - 2 - H319
STOT SE - 3 - H335
Asp. Tox. - 1 - H304
Aquatic Chronic - 2 - H411
	CASRN
108-67-8
EC-No.
203-604-4
Index-No.
601-025-00-5	< 1.0 %	1,3,5-Trimethylbenzene	Flam. Liq. - 3 - H226
Skin Irrit. - 2 - H315
Eye Irrit. - 2 - H319
STOT SE - 3 - H335
Asp. Tox. - 1 - H304
Aquatic Chronic - 2 - H411
	CASRN
91-20-3
EC-No.
202-049-5
Index-No.
601-052-00-2	< 1.0 %	Naphthalene	Acute Tox. - 4 - H302
Carc. - 2 - H351
Aquatic Acute - 1 - H400
Aquatic Chronic - 1 - H410
	For the full text of the H-Statements mentioned in this Section, see Section 16.

4. FIRST AID MEASURES
Description of first aid measures
General advice: First Aid responders should pay attention to self-protection and use the recommended protective clothing (chemical resistant gloves, splash protection).  If potential for exposure exists refer to Section 8 for specific personal protective equipment.  

Inhalation: Move person to fresh air. If person is not breathing, call an emergency responder or ambulance, then give artificial respiration; if by mouth to mouth use rescuer protection (pocket mask etc). Call a poison control center or doctor for treatment advice.  If breathing is difficult, oxygen should be administered by qualified personnel.  

Skin contact: Take off contaminated clothing. Wash skin with soap and plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice.  Wash clothing before reuse. Shoes and other leather items which cannot be decontaminated should be disposed of properly.  Suitable emergency safety shower facility should be available in work area.  

Eye contact: Hold eyes open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eyes. Call a poison control center or doctor for treatment advice.  Suitable emergency eye wash facility should be available in work area.  

Ingestion: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by the poison control center or doctor.  Never give anything by mouth to an unconscious person.  

Most important symptoms and effects, both acute and delayed: Aside from the information found under Description of first aid measures (above) and Indication of immediate medical attention and special treatment needed (below), any additional important symptoms and effects are described in Section 11: Toxicology Information.

Indication of any immediate medical attention and special treatment needed
Notes to physician: Maintain adequate ventilation and oxygenation of the patient.  Respiratory symptoms, including pulmonary edema, may be delayed. Persons receiving significant exposure should be observed 24-48 hours for signs of respiratory distress.  No specific antidote.  Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient.  Have the Safety Data Sheet, and if available, the product container or label with you when calling a poison control center or doctor, or going for treatment.  

5. FIREFIGHTING MEASURES
Suitable extinguishing media: Water fog or fine spray.  Dry chemical fire extinguishers.  Carbon dioxide fire extinguishers.  Foam.  Alcohol resistant foams (ATC type) are preferred. General purpose synthetic foams (including AFFF) or protein foams may function, but will be less effective.  

Unsuitable extinguishing media: No data available

Special hazards arising from the substance or mixture
Hazardous combustion products: During a fire, smoke may contain the original material in addition to combustion products of varying composition which may be toxic and/or irritating.  

Unusual Fire and Explosion Hazards:   Container may rupture from gas generation in a fire situation.  Violent steam generation or eruption may occur upon application of direct water stream to hot liquids.  Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur.  Dense smoke is produced when product burns.  

Advice for firefighters
Fire Fighting Procedures: Keep people away.  Isolate fire and deny unnecessary entry.  Stay upwind. Keep out of low areas where gases (fumes) can accumulate.  Use water spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has passed.  Fight fire from protected location or safe distance. Consider the use of unmanned hose holders or monitor nozzles.  Immediately withdraw all personnel from the area in case of rising sound from venting safety device or discoloration of the container.  Burning liquids may be extinguished by dilution with water.  Do not use direct water stream. May spread fire.  Eliminate ignition sources.  Move container from fire area if this is possible without hazard.  Burning liquids may be moved by flushing with water to protect personnel and minimize property damage.  Contain fire water run-off if possible. Fire water run-off, if not contained, may cause environmental damage.  Review the "Accidental Release Measures" and the "Ecological Information" sections of this (M)SDS.  

Special protective equipment for firefighters: Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves).  Avoid contact with this material during fire fighting operations. If contact is likely, change to full chemical resistant fire fighting clothing with self-contained breathing apparatus.  If this is not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight fire from a remote location.  For protective equipment in post-fire or non-fire clean-up situations, refer to the relevant sections.  

6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures: Isolate area.  Keep unnecessary and unprotected personnel from entering the area.  Keep personnel out of low areas.  Keep upwind of spill.  Ventilate area of leak or spill.  No smoking in area.  Vapor explosion hazard. Keep out of sewers.  Eliminate all sources of ignition in vicinity of spill or released vapor to avoid fire or explosion.  Ground and bond all containers and handling equipment.  Refer to section 7, Handling, for additional precautionary measures.  Use appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection.  

Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information.  Spills or discharge to natural waterways is likely to kill aquatic organisms.  

Methods and materials for containment and cleaning up: Contain spilled material if possible.  Pump with explosion-proof equipment. If available, use foam to smother or suppress.  Small spills:  Absorb with materials such as:  Clay.  Dirt.  Sand.  Sweep up.  Collect in suitable and properly labeled containers.  Large spills:  Contact Dow AgroSciences for clean-up assistance.  See Section 13, Disposal Considerations, for additional information.  

7. Handling and storage
Precautions for safe handling: Keep away from heat, sparks and flame.  Keep out of reach of children.  Do not swallow.  Avoid contact with eyes, skin, and clothing.  Avoid breathing vapor or mist.  Avoid prolonged or repeated contact with skin.  Wash thoroughly after handling.  Keep container closed.  Use with adequate ventilation.  No smoking, open flames or sources of ignition in handling and storage area.  Electrically ground and bond all equipment.  Containers, even those that have been emptied, can contain vapors. Do not cut, drill, grind, weld, or perform similar operations on or near empty containers.  Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur.  Use of non-sparking or explosion-proof equipment may be necessary, depending upon the type of operation.  See Section 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION.  

Conditions for safe storage: Store in a dry place.  Store in original container.  Keep container tightly closed when not in use.  Do not store near food, foodstuffs, drugs or potable water supplies.  Minimize sources of ignition, such as static build-up, heat, spark or flame.  

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
If exposure limits exist, they are listed below.  If no exposure limits are displayed, then no values are applicable.
Component	Regulation	Type of listing	Value/Notation	Heavy aromatic naphtha	ACGIH	TWA 	200 mg/m3  , total hydrocarbon vapor		Dow IHG	TWA 	100 mg/m3  		Dow IHG	STEL 	300 mg/m3  	Solvent naphtha (petroleum), heavy aromatic	ACGIH	TWA 	200 mg/m3  , total hydrocarbon vapor		Dow IHG	TWA 	100 mg/m3  		Dow IHG	STEL 	300 mg/m3  	1,2,4-Trimethylbenzene	ACGIH	TWA 	  25 ppm		2000/39/EC	TWA 	100 mg/m3  20 ppm	1,3,5-Trimethylbenzene	ACGIH	TWA 	  25 ppm		2000/39/EC	TWA 	100 mg/m3  20 ppm	Naphthalene	ACGIH	TWA 	  10 ppm		ACGIH	TWA 	   SKIN		Dow IHG	TWA 	  10 ppm		Dow IHG	TWA 	   SKIN		Dow IHG	STEL 	  15 ppm		Dow IHG	STEL 	   SKIN		91/322/EEC	TWA 	50 mg/m3  10 ppm	
RECOMMENDATIONS IN THIS SECTION ARE FOR MANUFACTURING, COMMERCIAL BLENDING AND PACKAGING WORKERS. APPLICATORS AND HANDLERS SHOULD SEE THE PRODUCT LABEL FOR PROPER PERSONAL PROTECTIVE EQUIPMENT AND CLOTHING.  

Exposure controls
Engineering controls: Use engineering controls to maintain airborne level below exposure limit requirements or guidelines.  If there are no applicable exposure limit requirements or guidelines, use only with adequate ventilation.  Local exhaust ventilation may be necessary for some operations.  

Individual protection measures
Eye/face protection: Use chemical goggles.  Chemical goggles should be consistent with EN 166 or equivalent.  
Skin protection
Hand protection: Use chemical resistant gloves classified under Standard EN374: Protective gloves against chemicals and micro-organisms.  Examples of preferred glove barrier materials include:  Polyethylene.  Ethyl vinyl alcohol laminate ("EVAL").  Polyvinyl chloride ("PVC" or "vinyl").  Styrene/butadiene rubber.  Viton.  Examples of acceptable glove barrier materials include:  Butyl rubber.  Chlorinated polyethylene.  Natural rubber ("latex").  Neoprene.  Nitrile/butadiene rubber ("nitrile" or "NBR").  When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time greater than 240 minutes according to EN 374) is recommended.  When only brief contact is expected, a glove with a protection class of 3 or higher (breakthrough time greater  than 60 minutes according to EN 374) is recommended.  Glove thickness alone is not a good indicator of the level of protection a glove provides against a chemical substance as this level of protection is also highly dependent on the specific composition of the material that the glove is fabricated from. The thickness of the glove must, depending on model and type of material, generally be more than 0.35 mm to offer sufficient protection for prolonged and frequent contact with the substance. As an exception to this general rule it is known that multilayer laminate gloves may offer prolonged protection at thicknesses less than 0.35 mm. Other glove materials with a thickness of less than 0.35 mm may offer sufficient protection when only brief contact is expected.  NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier.  
Other protection: Use protective clothing chemically resistant to this material.  Selection of specific items such as face shield, boots, apron, or full body suit will depend on the task.  
Respiratory protection: Respiratory protection should be worn when there is a potential to exceed the exposure limit requirements or guidelines.  If there are no applicable exposure limit requirements or guidelines, use an approved respirator.  Selection of air-purifying or positive-pressure supplied-air will depend on the specific operation and the potential airborne concentration of the material.  For emergency conditions, use an approved positive-pressure self-contained breathing apparatus.  
Use the following CE approved air-purifying respirator:  Organic vapor cartridge with a particulate pre-filter, type AP2.  

See SECTION 7: Handling and storage and SECTION 13: Disposal considerations for measures to prevent excessive environmental exposure during use and waste disposal.

9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Physical state	Liquid.  	ColorYellow to brown  Odor	Aromatic  	Odor Threshold	No data available	pH	4.8   1% CIPAC MT 75 (1% aqueous suspension)Melting point/range	Not applicableFreezing point	No test data availableBoiling point (760 mmHg)	No test data availableFlash point	closed cup 53.6 °C Pensky-Martens Closed Cup ASTM D 93 Evaporation Rate (Butyl Acetate = 1)	No test data availableFlammability (solid, gas)	Not ApplicableLower explosion limit	No test data available  Upper explosion limit	No test data available  Vapor Pressure	 No test data availableRelative Vapor Density (air = 1)	No test data available 	Relative Density (water = 1)	0.97  at 20 °C  / 4 °C  	Water solubility	emulsifiable  	Partition coefficient: n-octanol/water	No data available  	Auto-ignition temperature	340 °C  EC Method A15  	Decomposition temperature	No test data available  	Kinematic Viscosity	306.0 mm2/s at 40 °C 	Explosive properties	No Mechanical Impact @ 8 inches	Oxidizing properties	No 	Liquid Density	No test data available	Molecular weight	No data available	Surface tension	30 mN/m  at25 °C 	
NOTE:  The physical data presented above are typical values and should not be construed as a specification.
10. STABILITY AND REACTIVITY
Reactivity: No dangerous reaction known under conditions of normal use.  

Chemical stability: Thermally stable at typical use temperatures.  

Possibility of hazardous reactions: Polymerization will not occur.  
 
Conditions to avoid: Some components of this product can decompose at elevated temperatures.  Generation of gas during decomposition can cause pressure in closed systems.  

Incompatible materials: None known.  

Hazardous decomposition products:  Decomposition products depend upon temperature, air supply and the presence of other materials.  Toxic gases are released during decomposition.  
11. TOXICOLOGICAL INFORMATION

Toxicological information appears in this section when such data is available. 

Acute toxicity
Acute oral toxicity
Low toxicity if swallowed.  Small amounts swallowed incidentally as a result of normal handling operations are not likely to cause injury; however, swallowing larger amounts may cause injury.  

As product:  
LD50. Rat. female. 1,030 mg/kg  

Acute dermal toxicity
Prolonged skin contact is unlikely to result in absorption of harmful amounts.  

As product:  
LD50. Rat. male and female. > 5,000 mg/kg 

Acute inhalation toxicity
Prolonged excessive exposure to mist may cause serious adverse effects, even death.  Signs and symptoms of excessive exposure may include:  Anesthetic or narcotic effects.  May cause central nervous system effects.  Sweating.  Nausea and/or vomiting.  May cause pulmonary edema (fluid in the lungs.)  

The LC50 has not been determined.  
LC50. Rat. 4 Hour. dust/mist. > 2 mg/l  Estimated. 

Skin corrosion/irritation
Brief contact may cause slight skin irritation with local redness.

Serious eye damage/eye irritation
May cause moderate eye irritation.
May cause slight corneal injury.

Sensitization
Has demonstrated the potential for contact allergy in mice.
Did not cause allergic skin reactions when tested in guinea pigs.

For respiratory sensitization:
No relevant data found.

Specific Target Organ Systemic Toxicity (Single Exposure)
May cause drowsiness or dizziness.

Specific Target Organ Systemic Toxicity (Repeated Exposure)
For the active ingredient(s):
In animals, effects have been reported on the following organs:
Liver.
Contains component(s) which have been reported to cause effects on the following organs in animals:
Respiratory tract.
Lung.
Gastrointestinal tract.
Thyroid.
Urinary tract.
Kidney.
Dose levels producing these effects were many times higher than any dose levels expected from exposure due to use.

Carcinogenicity
For similar active ingredient(s).  Dinocap.  Did not cause cancer in laboratory animals.  

Teratogenicity
For the active ingredient(s):  Did not cause birth defects or other effects in the fetus even at doses which caused toxic effects in the mother.  

For the minor component(s)  Has been toxic to the fetus in laboratory animals at doses toxic to the mother.  Did not cause birth defects in laboratory animals.  

Reproductive toxicity
For similar active ingredient(s).  Dinocap.  In animal studies, did not interfere with reproduction.  

Mutagenicity
For the active ingredient(s):  In vitro genetic toxicity studies were negative.  Animal genetic toxicity studies were negative.  

Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard.  

12. ECOLOGICAL INFORMATION

Ecotoxicological information appears in this section when such data is available.

Toxicity
Acute toxicity to fish
Material is very toxic to aquatic organisms (LC50/EC50/IC50 below 1 mg/L in the most sensitive species).

LC50. Lepomis macrochirus (Bluegill sunfish). static test. 96 Hour. 0.11 mg/l. OECD Test Guideline 203 or Equivalent

Acute toxicity to aquatic invertebrates
EC50. Daphnia magna (Water flea). Static. 48 Hour. 0.00306 mg/l

Toxicity to Above Ground Organisms
Material is practically non-toxic to birds on an acute basis (LD50 > 2000 mg/kg).

oral LD50. Colinus virginianus (Bobwhite quail). 2532mg/kg bodyweight.

oral LD50. Apis mellifera (bees). 48 Hour. 84.8micrograms/bee

contact LD50. Apis mellifera (bees). 48 Hour. 90micrograms/bee

Toxicity to soil-dwelling organisms
LC50. Eisenia fetida (earthworms). 14 d. survival. 210 mg/kg

Persistence and degradability

Meptyldinocap
Biodegradability: Material is expected to biodegrade very slowly (in the environment).  Fails to pass OECD/EEC tests for ready biodegradability.  
10-day Window: Fail  
Biodegradation:  18.4 % 
Exposure time: 28 d 
Method: OECD Test Guideline 301F or Equivalent  

Stability in Water (1/2-life)
. half-life. 30.4 d. pH 7. Half-life Temperature 20 °C

Heavy aromatic naphtha
Biodegradability: Material is inherently biodegradable (reaches > 20% biodegradation in OECD test(s) for inherent biodegradability).  

Benzenesulfonic acid, mono-C11-13-branched alkyl derivs., calcium salts
Biodegradability: Material is expected to biodegrade very slowly (in the environment).  Fails to pass OECD/EEC tests for ready biodegradability.  
10-day Window: Fail  
Biodegradation:  2.9 % 
Exposure time: 28 d 
Method: OECD Test Guideline 301E or Equivalent  

Solvent naphtha (petroleum), heavy aromatic
Biodegradability: For similar material(s):  Biodegradation may occur under aerobic conditions (in the presence of oxygen).  Based on stringent OECD test guidelines, this material cannot be considered as readily biodegradable; however, these results do not necessarily mean that the material is not biodegradable under environmental conditions.  

Biodegradation:  58.6 % 
Exposure time: 28 d 
Method: OECD Test Guideline 301F  

1,2,4-Trimethylbenzene
Biodegradability: Material is ultimately biodegradable (reaches > 70% mineralization in OECD test(s) for inherent biodegradability).  

Biodegradation:  100 % 
Exposure time: 1 d 

1,3,5-Trimethylbenzene
Biodegradability: Based on stringent OECD test guidelines, this material cannot be considered as readily biodegradable; however, these results do not necessarily mean that the material is not biodegradable under environmental conditions.  
10-day Window: Not applicable  
Biodegradation:  0 % 
Exposure time: 28 d 
Method: OECD Test Guideline 301C or Equivalent  
10-day Window: Not applicable  
Biodegradation:  50 % 
Exposure time: 4.4 d 
Method: Calculated.  

Naphthalene
Biodegradability: Material is expected to be readily biodegradable.  

Bioaccumulative potential

Meptyldinocap
Bioaccumulation: Bioconcentration potential is moderate (BCF between 100 and 3000 or Log Pow between 3 and 5).  
Partition coefficient: n-octanol/water(log Pow): 6.55 at 25 °C 
Bioconcentration factor (BCF): 992  Lepomis macrochirus (Bluegill sunfish)  28 d  

Heavy aromatic naphtha
Bioaccumulation: For similar material(s):  Bioconcentration potential is high (BCF > 3000 or Log Pow between 5 and 7).  

Benzenesulfonic acid, mono-C11-13-branched alkyl derivs., calcium salts
Bioaccumulation: Bioconcentration potential is moderate (BCF between 100 and 3000 or Log Pow between 3 and 5).  
Partition coefficient: n-octanol/water(log Pow): 4.6 OECD Test Guideline 107 or Equivalent 

Solvent naphtha (petroleum), heavy aromatic
Bioaccumulation: For similar material(s):  Bioconcentration potential is high (BCF > 3000 or Log Pow between 5 and 7).  

1,2,4-Trimethylbenzene
Bioaccumulation: Bioconcentration potential is moderate (BCF between 100 and 3000 or Log Pow between 3 and 5).  
Partition coefficient: n-octanol/water(log Pow): 3.63 Measured 
Bioconcentration factor (BCF): 33 - 275  Cyprinus carpio (Carp)  56 d  Measured

1,3,5-Trimethylbenzene
Bioaccumulation: Bioconcentration potential is moderate (BCF between 100 and 3000 or Log Pow between 3 and 5).  
Partition coefficient: n-octanol/water(log Pow): 3.42 Measured 
Bioconcentration factor (BCF): 161  Pimephales promelas (fathead minnow)    Measured

Naphthalene
Bioaccumulation: Bioconcentration potential is moderate (BCF between 100 and 3000 or Log Pow between 3 and 5).  
Partition coefficient: n-octanol/water(log Pow): 3.3 Measured 
Bioconcentration factor (BCF): 40 - 300  Fish  28 d  Measured

Mobility in soil

Meptyldinocap
Expected to be relatively immobile in soil (Koc > 5000).
Partition coefficient (Koc): 58245 

Heavy aromatic naphtha
No relevant data found.

Benzenesulfonic acid, mono-C11-13-branched alkyl derivs., calcium salts
No relevant data found.

Solvent naphtha (petroleum), heavy aromatic
No data available.

1,2,4-Trimethylbenzene
Potential for mobility in soil is low (Koc between 500 and 2000).
Partition coefficient (Koc): 720 Estimated.

1,3,5-Trimethylbenzene
Potential for mobility in soil is low (Koc between 500 and 2000).
Partition coefficient (Koc): 741.65 Estimated.

Naphthalene
Potential for mobility in soil is medium (Koc between 150 and 500).
Partition coefficient (Koc): 240 - 1300 Measured

Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.  

Other adverse effects

Meptyldinocap
This substance is not on the Montreal Protocol list of substances that deplete the ozone layer.

Heavy aromatic naphtha
This substance is not on the Montreal Protocol list of substances that deplete the ozone layer.

Benzenesulfonic acid, mono-C11-13-branched alkyl derivs., calcium salts
This substance is not on the Montreal Protocol list of substances that deplete the ozone layer.

Solvent naphtha (petroleum), heavy aromatic
This substance is not on the Montreal Protocol list of substances that deplete the ozone layer.

1,2,4-Trimethylbenzene
This substance is not on the Montreal Protocol list of substances that deplete the ozone layer.

1,3,5-Trimethylbenzene
This substance is not on the Montreal Protocol list of substances that deplete the ozone layer.

Naphthalene
This substance is not on the Montreal Protocol list of substances that deplete the ozone layer.

13. DISPOSAL CONSIDERATIONS
Disposal methods: 
If wastes and/or containers cannot be disposed of according to the product label directions, disposal of this material must be in accordance with your local or area regulatory authorities.  This information presented below only applies to the material as supplied.  The identification based on characteristic(s) or listing may not apply if the material has been used or otherwise contaminated.  It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste identification and disposal methods in compliance with applicable regulations.  If the material as supplied becomes a waste, follow all applicable regional, national and local laws.  

14. TRANSPORT INFORMATION

Classification for ROAD and Rail transport:
Proper shipping name	FLAMMABLE LIQUID, N.O.S.(Meptyl Dinocap, Aromatic hydrocarbon)	UN number	UN  1993	Class	3	Packing group	III	Environmental hazards	Meptyl Dinocap	

Classification for SEA transport (IMO-IMDG):
Proper shipping name	FLAMMABLE LIQUID, N.O.S.(Meptyl Dinocap, Aromatic hydrocarbon)	UN number	UN  1993	Class	3	Packing group	III	Marine pollutant	Meptyl Dinocap	Transport in bulk according to Annex I or II of MARPOL 73/78 and the IBC or IGC Code	Consult IMO regulations before transporting ocean bulk	
Classification for AIR transport (IATA/ICAO):
Proper shipping name	Flammable liquid, n.o.s.(Meptyl Dinocap, Aromatic hydrocarbon)	UN number	UN  1993	Class	3	Packing group	III	

This information is not intended to convey all specific regulatory or operational requirements/information relating to this product.  Transportation classifications may vary by container volume and may be influenced by regional or country variations in regulations.  Additional transportation system information can be obtained through an authorized sales or customer service representative.  It is the responsibility of the transporting organization to follow all applicable laws, regulations and rules relating to the transportation of the material.

15. REGULATORY INFORMATION

Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances.
Listed in Regulation: FLAMMABLE LIQUIDS
Number in Regulation: P5c
5,000 t
50,000 t
Listed in Regulation: ENVIRONMENTAL HAZARDS
Number in Regulation: E1
100 t
200 t
Listed in Regulation: Petroleum products: (a) gasolines and naphthas, (b) kerosenes (including jet fuels), (c) gas oils (including diesel fuels, home heating oils and gas oil blending streams),(d) heavy fuel oils (e) alternative fuels serving the same purposes and with similar properties as regards flammability and environmental hazards as the products referred to in points (a) to (d)
Number in Regulation: 34
2,500 t
25,000 t

Classification and labeling have been performed according to Regulation (EC) No 1272/2008.
16. OTHER INFORMATION

Full text of H-Statements referred to under sections 2 and 3.
H226Flammable liquid and vapour.	H302Harmful if swallowed.	H304May be fatal if swallowed and enters airways.	H312Harmful in contact with skin.	H315Causes skin irritation.	H317May cause an allergic skin reaction.	H318Causes serious eye damage.	H319Causes serious eye irritation.	H332Harmful if inhaled.	H335May cause respiratory irritation.	H336May cause drowsiness or dizziness.	H351Suspected of causing cancer.	H400Very toxic to aquatic life.	H410Very toxic to aquatic life with long lasting effects.	H411Toxic to aquatic life with long lasting effects.	
Revision
Identification Number: 99078467 / A285 / Issue Date: 03/08/2018 / Version: 3.0
DAS Code: GF-1478
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this document.

Legend
2000/39/EC	Europe. Commission Directive 2000/39/EC establishing a first list of indicative occupational exposure limit values	91/322/EEC	Europe. Commission Directive 91/322/EEC on establishing indicative limit values	ACGIH	USA. ACGIH Threshold Limit Values (TLV)	Dow IHG	Dow Industrial Hygiene Guideline	SKIN	Absorbed via skin	STEL	Short term exposure limit	TWA	Limit Value - eight hours	Acute Tox.	Acute toxicity	Aquatic Acute	Acute aquatic toxicity	Aquatic Chronic	Chronic aquatic toxicity	Asp. Tox.	Aspiration hazard	Carc.	Carcinogenicity	Eye Dam.	Serious eye damage	Eye Irrit.	Eye irritation	Flam. Liq.	Flammable liquids	Skin Irrit.	Skin irritation	Skin Sens.	Skin sensitisation	STOT SE	Specific target organ toxicity - single exposure	
Full text of other abbreviations
ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways; ADR - European Agreement concerning the International Carriage of Dangerous Goods by Road; AICS - Australian Inventory of Chemical Substances; ASTM - American Society for the Testing of Materials; bw - Body weight; CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Canada); ECHA - European Chemicals Agency; EC-Number - European Community number; ECx - Concentration associated with x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; n.o.s. - Not Otherwise Specified; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RID - Regulations concerning the International Carriage of Dangerous Goods by Rail; SADT - Self-Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative

Information Source and References
This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from information supplied by internal references within our company.

DOW AGROSCIENCES S.A.S. urges each customer or recipient of this (M)SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this (M)SDS and any hazards associated with the product.  The information herein is provided in good faith and believed to be accurate as of the effective date shown above.  However, no warranty, express or implied, is given.  Regulatory requirements are subject to change and may differ between various locations. It is the buyer's/user's responsibility to ensure that his activities comply with all federal, state, provincial or local laws.  The information presented here pertains only to the product as shipped.  Since conditions for use of the product are not under the control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the safe use of this product.  Due to the proliferation of sources for information such as manufacturer-specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other than ourselves.  If you have obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current, please contact us for the most current version.    

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